MALEIC
ACID |
PRODUCT
IDENTIFICATION
|
CAS
NO. |
110-16-7 |
|
EINECS
NO. |
203-742-5 |
FORMULA |
HOOCCH=CHCOOH |
MOL
WT. |
116.07 |
H.S.
CODE |
2917.19 |
TOXICITY
|
Oral
rat LD50: 708 mg/kg |
SYNONYMS |
Hydroxysuccinic
Acid; |
2-butenedioic
acid; cis-1,2-ethenedicarboxylic acid; cis-2-butenedioic
acid; cis-butenedioic acid; cis-ethene-1,2-dicarboxylic
acid; cis-maleic acid; Malenic Acid; Toxilic acid; (Z)-1,2-ethenedicarboxylic
acid; (Z)-2-butenedioic acid; |
SMILES
|
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
white
crystals |
MELTING
POINT |
130
- 131 C
|
BOILING
POINT |
Decomposes |
SPECIFIC
GRAVITY |
1.59 |
SOLUBILITY
IN WATER |
soluble |
pH |
<
7 |
VAPOR
DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health:
3; Flammability: 0; Reactivity:
0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
>
100 C |
STABILITY |
Stable
under ordinary conditions |
APPLICATIONS
|
Maleic acid
(also called cis-butenedioic acid), a white crystals easily soluble in water,
acetone, and alcohol, is an unsaturated organic dibasic acid which carboxylic
acid groups are next to each other in the cis form. Its trans form isomer is
fumaric acid, both are used in making polyesters, alkyd resins, plasticizers and
lubricating oils. Maleic anhydride is the main source of maleic acid produced by
the hydration. Maleic anhydride is prepared commercially by the oxidation of
benzene or by the reaction of C4 (butane) with oxygen in the presence
of vanadium catalyst. The physical properties of maleic acid
and fumaric acid are very different each other. The cis isomer is the less
stable. Maleic acid is used in the preparation of fumaric acid by
catalytic isomerization. and other chemical products as a carboxylating agent.
It is used as an oil and fat preservative and food acidulant. |
SALES
SPECIFICATION |
APPEARANCE
|
clear
to pale yellow liquid |
PURITY |
99.0%
min
|
HEAVY
METALS |
10ppm
max
|
Fe
|
5ppm
max
|
RESIDUE
ON IGNITION
|
0.5%
max
|
WATER |
1.0%
max
|
TRANSPORTATION |
PACKING |
25kgs
in bag |
HAZARD
CLASS |
8
(Packing
Group: III) |
UN
NO. |
3261 |
OTHER
INFORMATION |
Hazard Symbols: XN, Risk Phrases: 22-36/37/38
,
Safety Phrases: 26-28A-37 UNSATURATED ALIPHATIC CARBOXYLIC ACIDS (SHORT
CHAIN) |
|